Synthesis of N-(2-triphenylstannylethyl) amines and their reactivities

Y Sato, Y Ban, H Shirai

Index: Sato, Y.; Ban, Y.; Shirai, H. Journal of Organic Chemistry, 1973 , vol. 38, p. 4373 - 4378

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Citation Number: 7

Abstract

The reactions of seven iV-(2-triphenylstannylethyl) amines (3a-g), prepared from the corresponding 2-chloroethylamines (la-e, g) and triphenyltinlithium (2), with methyl halides (MeX) or hydrogen halides (HX) were investigated. In the case of X= I or Br, the quaternary ammonium salts or the amine hydrohalides,. produced from A'-(2-triphenylstannylethy1) alkylamines (3a and 3b), were unstable and were cleaved by nucleophilic attack of X-at tin ...