Regiochemistry of alkenylsilyl and alkenyldisilanyl radical cyclizations
TJ Barton, A Revis
Index: Barton,T.J.; Revis,A. Journal of the American Chemical Society, 1984 , vol. 106, p. 3802
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Citation Number: 32
Abstract
The purpose of the work reported herein was to determine whether the Baldwin-Beckwith rules could be extended to the cyclizations of alkenyl silicon-centered radicals. The question was whether radicals of type 1 would undergo kinetically controlled exo cyclization to afford 2 or thermodynamically controlled endo cyclization to afford 3.
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