Palladium??Catalyzed Carbonylative α??Arylation for Accessing 1, 3??Diketones
TM Gøgsig, RH Taaning, AT Lindhardt…
Index: Gogsig, Thomas M.; Taaning, Rolf H.; Lindhardt, Anders T.; Skrydstrup, Troels Angewandte Chemie - International Edition, 2012 , vol. 51, # 3 p. 798 - 801
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Citation Number: 53
Abstract
The palladium-catalyzed coupling between aryl halides and enolizable reagents has become a convenient method for the construction of C (sp2)–C (sp3) bonds to generate allylic and benzylic carbonyl derivatives, which are found in a vast number of pharmaceuticals and bioactive compounds.[1] Owing to the significant contributions from the groups of Hartwig, Buchwald, and others, efficient protocols for the direct α-arylation of ...
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