Monatshefte für Chemie/Chemical Monthly

Darstellung und Eigenschaften von Trimethyl-(dialkylamidosulfonyl)-ammoniumhalogeniden

H Safari, A Blaschette

Index: Safari,H.; Blaschette,A. Monatshefte fuer Chemie, 1970 , vol. 101, p. 1373 - 1387

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Citation Number: 3

Abstract

Abstract Treatment of dialkylamidosulphonyl chlorides or bromides with trimethylamine affords stable crystalline 1∶ 1 addition compounds of the general formula [R 2 NSO 2 N (CH 3) 3]+ X−(cf. Table 1). Evidence for this formulation is obtained from IR spectra. A striking difference between these compounds and the parent sulphonyl halides is the enhanced reactivity of the halogen groups. The thermal degradation and the reactions of the ...