Unusual reaction course of styrenes to 2-arylethyltriphenylphosphonium salts
K Okuma, K Yoshitake, T Izaki, K Yoshida…
Index: Okuma, Kentaro; Yoshitake, Koichiro; Izaki, Toshiharu; Yoshida, Keiko; Shioji, Kosei Bulletin of the Chemical Society of Japan, 2007 , vol. 80, # 9 p. 1785 - 1790
Full Text: HTML
Citation Number: 3
Abstract
1-Arylethyltriphenylphosphonium bromides thermally rearranged to 2- arylethyltriphenylphosphonium bromides. Direct formation of 2-arylethylphosphonium bromides was achieved by reacting styrene, HBr, and triphenylphosphine. On the other hand, thermolysis of 1-indanyltriphenylphosphonium bromide gave indene and triphenylphosphonium bromide. From deuterium and 13 C-labeled experiments, the ...
Related Articles:
Thermal decomposition of triphenylphosphonium alkyl ester salts
[Castaneda, Fernando; Aliaga, Christian; Acuna, Cristina; Silva, Paul; Bunton, Clifford A. Phosphorus, Sulfur and Silicon and the Related Elements, 2008 , vol. 183, # 5 p. 1188 - 1208]