Halomethyl-metal compounds: XL. Trimethylsilyl-substituted bromomethyllithium and-magnesium reagents. Trimethyltindibromomethylmagnesium chloride

D Seyferth, RL Lambert, EM Hanson

Index: Seyferth,D. et al. Journal of Organometallic Chemistry, 1970 , vol. 24, p. 647 - 661

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Citation Number: 76

Abstract

Abstract The low temperature reactions of n-butyllithium with trimethyl (tribromomethyl) silane, trimethyl (dibromomethyl) silane and bis (trimethylsilyl) dibromomethane served well in the preparation of trimethylsilyldibromomethyllithium, trimethylsilylbromomethyllithium and bis (trimethylsilyl) bromomethyllithium, respectively. The low temperature reaction of isopropylmagnesium chloride in THF with trimethyl (tribromomethyl) silane and trimethyl ( ...