Perhydroazulenes. 5. Preparation of Perhydroazul-9 (10)-en-4-one
…, JHC Lee, D VanDerveer, JE Wissinger
Index: House, Herbert O.; Lee, Joseph H. C.; VanDerveer, Don; Wissinger, Jane E. Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5285 - 5288
Full Text: HTML
Citation Number: 13
Abstract
In order to achieve selective y-substitution of a $-unsaturated esters, we investigated the directive effect of silicon in the reaction of various electrophiles with a-trimethylsilyl P, y- unsaturated esters. These esters were prepared by nickel-catalyzed vinylation reactions of the lithium enolate of ethyl a-(trimethylsily1) acetate. The a-silyl P, y-unsaturated esters reacted with a variety of electrophiles (aldehydes, ketones, acetals, ketals, acid chlorides, ...
Related Articles:
A catalytic method for α-glycol cleavage
[Barton, Derek H. R.; Motherwell, William B.; Stobie, Alan Journal of the Chemical Society, Chemical Communications, 1981 , # 23 p. 1232 - 1233]
A catalytic method for α-glycol cleavage
[Barton, Derek H. R.; Motherwell, William B.; Stobie, Alan Journal of the Chemical Society, Chemical Communications, 1981 , # 23 p. 1232 - 1233]
[Gleiter, Rolf; Karcher, Michael; Jahn, Reiner; Irngartinger, Hermann Chemische Berichte, 1988 , vol. 121, p. 735 - 740]
[Gleiter, Rolf; Karcher, Michael; Jahn, Reiner; Irngartinger, Hermann Chemische Berichte, 1988 , vol. 121, p. 735 - 740]
Stereochemically controlled syntheses of some bicyclo [n. 3.0] alkane-1-carboxylic acids
[Warnhoff,E.W. et al. Canadian Journal of Chemistry, 1978 , vol. 56, p. 93 - 98]