Formation of iodides and esters from alcohols and tributyldiiodophosphorane and diiodotriphenylphosphorane
RK Haynes, M Holden
Index: Haynes, Richard K.; Holden, Malcolm Australian Journal of Chemistry, 1982 , vol. 35, # 3 p. 517 - 524
Full Text: HTML
Citation Number: 28
Abstract
Abstract Tributyldiiodophosphorane and diiodotriphenylphosphorane, prepared in situ from the corresponding phosphine and iodine, are generally able to convert primary and secondary alcohols into iodides at room temperature in diethyl ether or benzene containing two equivalents of hexamethylphosphoric triamide. Tertiary alcohols, as gauged by the lack of reactivity of t-butyl alcohol, are, however, inert to these iodinating agents. 6- ...
Related Articles:
An Alternative Method for the Highly Selective Iodination of Alcohols Using a CsI/BF3· Et2O System
[Hayat, Safdar; Atta-Ur-Rahman; Khan, Khalid Mohammed; Choudhary, M. Iqbal; Maharvi, Ghulam Murtaza; Zia-Ullah; Bayer, Ernst Synthetic Communications, 2003 , vol. 33, # 14 p. 2531 - 2540]
Rh (I)-catalyzed Pauson–Khand reaction of 1-phenylsulfonyl-1, 2-octadien-7-yne derivatives
[Inagaki, Fuyuhiko; Kawamura, Takamasa; Mukai, Chisato Tetrahedron, 2007 , vol. 63, # 24 p. 5154 - 5160]