A Safe and Efficient Procedure to Prepare Alkyl and Alkoxyalkyl Chlorides and Dichlorides by Catalytic Decomposition of the Corresponding Alkyl and Alkoxyalkyl …

…, S Thiébaud, E Borredon, P Le Gars

Index: Violleau; Thiebaud; Borredon; Le Gars Synthetic Communications, 2001 , vol. 31, # 3 p. 367 - 373

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Abstract

Small amounts of hexabutylguanidinium chloride (0.01 mol%) decomposes pure chloroformates or bischloroformates with different lengths of carbon chains by a semicontinuous process to diminish run-away risk, leading to chloride compounds with high yield and purity.