Journal of Fluorine Chemistry

One-pot synthesis of quinoline-4-carboxylic acid derivatives in water: Ytterbium perfluorooctanoate catalyzed Doebner reaction

LM Wang, L Hu, HJ Chen, YY Sui, W Shen

Index: Wang, Li-Min; Hu, Liang; Chen, Hong-Juan; Sui, Yuan-Yuan; Shen, Wei Journal of Fluorine Chemistry, 2009 , vol. 130, # 4 p. 406 - 409

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Citation Number: 24

Abstract

Ytterbium perfluorooctanoate [Yb (PFO) 3] has been proved to be an efficient catalyst for Doebner reaction of pyruvic acid, aldehydes and amines under mild conditions in water to afford quinoline-4-caboxylic acid derivatives with three component one-pot method in good yields. The process is operationally simple and environmentally benign and the catalyst has readily been recycled for several times with consistent activity. Furthermore, a plausible ...

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