Tetrahedron letters

Iodotrimethylsilane: A mild and efficient reagent for the reduction of azides to amines

A Kamal, NV Rao, E Laxman

Index: Kamal, Ahmed; Rao, N. Venugopal; Laxman Tetrahedron Letters, 1997 , vol. 38, # 39 p. 6945 - 6948

Full Text: HTML

Citation Number: 51

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Chlorotrimethylsilane — sodium iodide reagent (in situ generation of iodotrimethylsilane)in acetonitrile reduces alkyl and aryl/aroyl azides to the corresponding amines/amides in excellent yields under neutral and mild conditions. ... The hydrolytic susceptibility of the Si-I bond in ...

Related Articles:

Efficient and Selective Room??Temperature Gold??Catalyzed Reduction of Nitro Compounds with CO and H2O as the Hydrogen Source

[He, Lin; Wang, Lu-Cun; Sun, Hao; Ni, Ji; Cao, Yong; He, Yong; Fan, Kang-Nian Angewandte Chemie - International Edition, 2009 , vol. 48, # 50 p. 9538 - 9541]

Chemoselective reductive alkylation of ammonia with carbonyl compounds: synthesis of primary and symmetrical secondary amines

[Miriyala, Bruhaspathy; Bhattacharyya, Sukanta; Williamson, John S. Tetrahedron, 2004 , vol. 60, # 7 p. 1463 - 1471]

One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination

[Kabalka, George W.; Wang, Zhe; Goudgaon, Nganna M. Synthetic Communications, 1989 , vol. 19, # 13-14 p. 2409 - 2414]

Metal??Free Conversion of Methane and Cycloalkanes to Amines and Amides by Employing a Borylnitrene

[Angewandte Chemie - International Edition, , vol. 47, # 25 p. 4744 - 4747]

Organoboranes for synthesis. 7. An improved general synthesis of primary amines from alkenes via hydroboration-organoborane chemistry

[Tetrahedron, , vol. 43, # 18 p. 4071 - 4078]

More Articles...