Synthesis of Heterobimetallic Group 13 Compounds via Oxidative Addition Reaction of Gallanediyl LGa and InEt3

…, D Bläser, C Wölper, S Schulz

Index: Gondzik; Schulz; Blaeser; Woelper Chemical Communications, 2014 ,  vol. 50,  # 10  p. 1189 - 1191

Full Text: HTML

Citation Number: 4

Abstract

Equimolar amounts of LGa (L=[(2, 6-i-Pr2-C6H3) NC (Me)] 2CH) and InEt3 were found to react with insertion into the In–carbon bond and formation of LGa (Et) InEt2 (1), while in the presence of the N-heterocyclic carbene I t-Bu [C (N t-Bu2CH) 2], the base-stabilized