Formation of benzylic chlorides by rearrangement of cycloheptatrienes with tellurium tetrachloride
M Albeck, T Tamari, M Sprecher
Index: Albeck, Michael; Tamari, Tova; Sprecher, Milon Journal of Organic Chemistry, 1983 , vol. 48, # 13 p. 2276 - 2278
Full Text: HTML
Citation Number: 7
Abstract
The rearrangement of cycloheptatrienes and alkyl cycloheptatrienes to substituted benzenes has been reported to proceed photochemically, or thermally at higher temperatures.'For the latter conditions a radical pathway has been postulated. 24 Fohlischs has presented evidence for the operation of ionic pathways in the isomerization and in the solvolysis of chloro-and bromocycloheptatrienes to benzyl halides or ethers, etc. Reaction ...
Related Articles:
[Chaudhari, Sachin S.; Akamanchi, Krishnacharya G. Synlett, 1999 , # 11 p. 1763 - 1765]
[Kajigaeshi, Shoji; Kakinami, Takaaki; Moriwaki, Masayuki; Tanaka, Toshio; Fujisaki, Shizuo Tetrahedron Letters, 1988 , vol. 29, # 45 p. 5783 - 5786]
[Angewandte Chemie - International Edition, , vol. 43, # 11 p. 1414 - 1416]
The reaction between acyl halides and alcohols: Alkyl halide vs. Ester formation
[Strazzolini, Paolo; Giumanini, Angelo G.; Verardo, Giancarlo Tetrahedron, 1994 , vol. 50, # 1 p. 217 - 254]
Exploratory study of the intermolecular reactivity of excited diphenylmethyl radicals
[Journal of the American Chemical Society, , vol. 107, # 15 p. 4396 - 4403]