Conversions of carbonyl compounds via their polymeric sulfonylhydrazones into alkenes, alkanes, and nitriles
H Kamogawa, A Kanzawa, M Kadoya, T Naito…
Index: Kamogawa, Hiroyoshi; Kanzawa, Asami; Kadoya, Masahiro; Naito, Takeshi; Nanasawa, Masato Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 3 p. 762 - 765
Full Text: HTML
Citation Number: 79
Abstract
Reins consisting of cross-linked poly (styrene-divinylbenzene) matrices functionalized with hydrazinosulfonyl groups react with aldehydes and ketones to form the sulfonylhydrazone derivatives. The extent of the reaction is sensitive to the type of resin and the bulk of the carbonyl compound. When heated strongly under alkaline conditions, the sulfonylhydrazones release the corresponding alkenes; upon the NaBH 4 or LiAlH 4 ...
Related Articles:
Direct one-step conversion of alcohols into nitriles
[Davis, Roman; Untch, Karl G. Journal of Organic Chemistry, 1981 , vol. 46, # 14 p. 2985 - 2987]
Metal ion photoinitiated addition of acetonitrile and methanol to olefins
[Bruno, Joseph W.; Marks, Tobin J.; Lewis, Frederick D. Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5580 - 5585]
[Masuda, Yuzuru; Hoshi, Masayuki; Arase, Akira Journal of the Chemical Society, Chemical Communications, 1989 , # 5 p. 266 - 267]
Pyrolysis of Esters. XVIII. Synthesis of Nitriles by Pyrolysis of Cyanoacetic Esters1
[Bailey; Daly Journal of the American Chemical Society, 1959 , vol. 81, p. 5397]
Electrochemical oxidation of acylsilanes and their tosylhydrazones
[Yoshida, Jun-ichi; Itoh, Masanori; Matsunaga, Shin-ichiro; Isoe, Sachihiko Journal of Organic Chemistry, 1992 , vol. 57, # 18 p. 4877 - 4882]