1, 3-Dimethyl-2-phenylbenzimidazoline as a novel and efficient reagent for mild reductive dehalogenation of. alpha.-halo carbonyl compounds and acid chlorides
H Chikashita, H Ide, K Itoh
Index: Chikashita, Hidenori; Ide, Hisao; Itoh, Kazuyoshi Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5400 - 5405
Full Text: HTML
Citation Number: 55
Abstract
1, 3-Dimethyl-2-phenylbenzimidazoline (DMBI) has been found to be a powerful, chemoselective, and useful reducing agent for mild reductive dehalogenation of a variety of a-halo carbonyl compounds (halo= Br, C1, F) and acid chlorides. The reduction of a-halo ketones, aldehydes, esters, lactones, and carboxylic acids with this new reagent in ether is quite selective and clean and generally proceeds in almost quantitative yields at moderate ...
Related Articles:
Oxidative Cleavage of Oximes with Silica??Gel??Supported Chromic Acid in Nonaqueous Media
[Ali, Mohammed Hashmat; Greene, Stacie; Wiggin, Candace J.; Khan, Saira Synthetic Communications, 2006 , vol. 36, # 12 p. 1761 - 1767]
Oxidation of Alkynes by the HOF⊙ CH3CN Complex
[Journal of Organic Chemistry, , vol. 65, # 25 p. 8816 - 8818]
Conversion of n, n-dimethylhydrazones to carbonyl compounds by clay-supported ferric nitrate
[Laszlo, Pierre; Polla, Eugenio Tetrahedron Letters, 1984 , vol. 25, # 31 p. 3309 - 3312]
Catalytic Deprotection of Acetals in Basic Solution with a Self??Assembled Supramolecular “Nanozyme”
[Angewandte Chemie - International Edition, , vol. 46, # 45 p. 8587 - 8589]
Carbanion rearrangements. Collision-induced dissociations of the enolate ion of heptan-4-one
[Stringer, Michael B.; Bowie, John H.; Holmes, John L. Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 3888 - 3893]