Reductive Elimination of Ether from T??Shaped, Monomeric Arylpalladium Alkoxides

JP Stambuli, Z Weng, CD Incarvito…

Index: Stambuli, James P.; Weng, Zhiqiang; Incarvito, Christopher D.; Hartwig, John F. Angewandte Chemie - International Edition, 2007 , vol. 46, # 40 p. 7674 - 7677

Full Text: HTML

Citation Number: 37

Abstract

Reductive elimination of ethers from organopalladium alkoxides is the C¿ O bond-forming step of the palladiumcatalyzed etherification of aryl halides.[1] At this time, examples of the reductive eliminations of ethers from isolated organopalladium alkoxide complexes are limited. Only reductive eliminations of alkyl aryl ethers from complexes generated in situ, reductive elimination of an oxygen heterocycle from a single oxapalladacycle,[2] reductive ...

1, 6-Diene Complexes of Palladium (0) and Platinum (0): Highly reactive sources for the naked metals and [L-M0] Fragments

[Journal of the American Chemical Society, , vol. 121, # 42 p. 9807 - 9823]

Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction

[Journal of the American Chemical Society, , vol. 130, # 46 p. 15549 - 15563]

Reductive Elimination of Ether from T??Shaped, Monomeric Arylpalladium Alkoxides

[Angewandte Chemie - International Edition, , vol. 46, # 40 p. 7674 - 7677]