PHOSPHORORGANISCHE VERBINDUNGEN 901: Methodische Ausgestaltung der PC und PS-Cyanolyse am Beispiel einiger Heterophosphoniumsalze

L Horner, M Jordan

Index: Horner, Leopold; Jordan, Manfred Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 215 - 220

Full Text: HTML

Citation Number: 11

Abstract

Abstract Aus Allylamido-phosphoniumsalzen wird durch trockenes Tetrabutylammoniumcyanid in Methylenchlorid die Allylgruppe unter Erhaltung der Konfiguration und Bildung von Phosphinigsäureamiden abgespalten (PC-Cyanolyse). Allyl- O-alkyl-phosphoniumsalze reagieren unter den oben genannten Bedingungen nach Arbusov, Allyl-S-alkyl-phosphoniumsalze aber unter Spaltung der PS-Bindung ab.(PS- ...

Related Articles:

Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine

[Tetrahedron Letters, , vol. 51, # 4 p. 698 - 701]

Preparation and application of air-stable P, N-bidentate ligands for the selective synthesis of δ-lactone via the palladium-catalyzed telomerization of 1, 3-butadiene …

[Journal of Organometallic Chemistry, , vol. 696, # 26 p. 4309 - 4314]

Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

[Tetrahedron, , vol. 67, # 32 p. 5825 - 5831]

Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

[Tetrahedron, , vol. 67, # 32 p. 5825 - 5831]

Rapid formation of triarylphosphines by microwave-assisted transition metal-catalyzed CP cross-coupling reactions

[Stadler, Alexander; Kappe, C. Oliver Organic Letters, 2002 , vol. 4, # 20 p. 3541 - 3543]

More Articles...