Highly efficient michael addition reaction of amines catalyzed by silica-supported aluminum chloride
…, Y Pourshojaei, F Aryanasab
Index: Saidi, Mohammad R.; Pourshojaei, Yaghoub; Aryanasab, Fezzeh Synthetic Communications, 2009 , vol. 39, # 6 p. 1109 - 1119
Full Text: HTML
Citation Number: 34
Abstract
Abstract Aliphatic and aromatic amines undergo smooth nucleophilic addition to α, β- unsaturated compounds in the presence of a catalytic amount of silica-supported aluminum chloride at 60° C and under solvent-free conditions to produce the corresponding β-amino compounds in excellent yields. This method is simple and convenient and works efficiently under mild conditions. This catalyst can used again without losing its activity three times.