Copper??Catalyzed Decarboxylation of Aromatic Carboxylic Acids: En Route to Milder Reaction Conditions
G Cahiez, A Moyeux, O Gager…
Index: Cahiez, Gerard; Moyeux, Alban; Gager, Olivier; Poizat, Mael Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 790 - 796
Full Text: HTML
Citation Number: 22
Abstract
Abstract The copper-catalyzed decarboxylation of carboxylic aromatic acids has been advantageously achieved by using aliphatic amines like tetramethylethylenediamine (TMEDA) or hexamethylenetetraamine (HMTA) as ligands instead of the aromatic heterocyclic amines (quinoline, phenanthroline) used until now. The improvement is significant since the reaction can be performed at a lower temperature (ca. 50 C less) and ...
Related Articles:
[Mao, Shu-Lan; Sun, Yue; Yu, Guang-Ao; Zhao, Cui; Han, Zhi-Jun; Yuan, Jia; Zhu, Xiaolei; Yang, Qihua; Liu, Sheng-Hua Organic and Biomolecular Chemistry, 2012 , vol. 10, # 47 p. 9410 - 9417]
Pd-catalyzed decarboxylative couplings of arenecarboxylic acids with aryl iodides
[Wang, Zhiyong; Ding, Qiuping; He, Xiaodan; Wu, Jie Tetrahedron, 2009 , vol. 65, # 24 p. 4635 - 4638]
[Goossen, Lukas J.; Rodriguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M. Journal of the American Chemical Society, 2007 , vol. 129, # 15 p. 4824 - 4833]
[Goossen, Lukas J.; Zimmermann, Bettina; Knauber, Thomas Angewandte Chemie - International Edition, 2008 , vol. 47, # 37 p. 7103 - 7106]
[Rao, Maddali L.N.; Jadhav, Deepak N.; Banerjee, Debasis Tetrahedron, 2008 , vol. 64, # 24 p. 5762 - 5772]