Effects of deuterium substitution on the rates of organic reactions. XI.. alpha.-and. beta.-Deuterium effects on the solvolysis rates of a series of substituted 1-phenylethyl …

VJ Shiner Jr, WE Buddenbaum, BL Murr…

Index: Shiner,V.J. et al. Journal of the American Chemical Society, 1968 , vol. 90, # 2 p. 418 - 426

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Citation Number: 77

Abstract

Abstract: The rates of solvolysis of eight different meta-and para-substituted 1-phenylethyl chlorides, three 1-phenylethyl bromides, and their ad and P-ds analogs have been measured in a series of acetone-water and ethanolwater mixtures with a precision of 0.1% or better using conductance techniques. The fact that 1-phenylethyl chloride and all of its more reactive derivatives, including the p-methoxy compound, have closely similar a- ...