The reactions of t-butoxyl with unsaturated hydrocarbons: Structure and reactivity of allylic radicals
MJ Cuthbertson, E Rizzardo, DH Solomon
Index: Cuthbertson, Matthew J.; Rizzardo, Ezio; Solomon, David H. Australian Journal of Chemistry, 1983 , vol. 36, # 10 p. 1957 - 1973
Full Text: HTML
Citation Number: 16
Abstract
Abstract A radical trapping technique employing 1, 1, 3, 3-tetramethylisoindolin-2-yloxy (1) as scavenger has been used to study the reactions of t-butoxy radicals with propene, 2- methylpropene, but-1-ene,(E)-and (Z)-but-2-ene, 3-methylbut-1-ene, buta-1, 3-diene and 2- methylbuta-1, 3-diene. Relative rates of double bond addition and of allylic hydrogen abstraction have been measured and are discussed, as are the relative stabilities of the ...
Related Articles:
Time-resolved observation of sequential bond cleavage in a gas-phase azoalkane
[Adams, J. Stephen; Burton, Katherine A.; Andrews, B. Kim; Weisman, R. Bruce; Engel, Paul S. Journal of the American Chemical Society, 1986 , vol. 108, # 25 p. 7935 - 7938]
Steric Factors in Liquid-Phase Oxidation of Olefins with iso Structure
[Voronenkov; Simonov; Yablonskii; Koshel' Russian Journal of Organic Chemistry, 2001 , vol. 37, # 3 p. 318 - 320]
Radikal??Stabilisierungsenergie–das MMEVBH??Kraftfeld
[Roth, Wolfgang R.; Staemmler, Volker; Neumann, Martin; Schmuck, Carsten Liebigs Annalen, 1995 , # 6 p. 1061 - 1118]
Radikal??Stabilisierungsenergie–das MMEVBH??Kraftfeld
[Roth, Wolfgang R.; Staemmler, Volker; Neumann, Martin; Schmuck, Carsten Liebigs Annalen, 1995 , # 6 p. 1061 - 1118]
Radikal??Stabilisierungsenergie–das MMEVBH??Kraftfeld
[Roth, Wolfgang R.; Staemmler, Volker; Neumann, Martin; Schmuck, Carsten Liebigs Annalen, 1995 , # 6 p. 1061 - 1118]