Reactions of α, β-unsaturated carboxylates, malonates and phenylacetates with manganese (III) acetate in the presence of chloride ions

H Yonemura, H Nishino, K Kurosawa

Index: Yonemura, Hiroshi; Nishino, Hiroshi; Kurosawa, Kazu Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 2 p. 809 - 811

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Citation Number: 7

Abstract

The reaction of alkyl (E)-3-phenylpropenoates with manganese (III) acetate in the presence of Cl− ions gave alkyl (Z)-2-chloro-3-phenylpropenoates and alkyl 2, 3-dichloro-3- phenylpropanoates. Ethyl (E)-2, 3-diphenylpropenoate yielded ethyl 2, 3-dichloro-2, 3- diphenylpropanoate. Alkyl 3, 3-diphenylpropenoates gave mainly alkyl 2-chloro-3, 3- diphenyl-propenoates. Ethyl 1-cyclohexenecarboxylate gave ethyl 1, 2- ...