Journal of Organometallic Chemistry

Reaction of active methylene compounds with butadiene catalysed by nickel complexes

R Baker, DE Halliday, TN Smith

Index: Baker,R. et al. Journal of Organometallic Chemistry, 1972 , vol. 35, p. C61 - C63

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Abstract

Reactions of active hydrogen compounds with 1, 3-butadiene have been reported with catalysis by both nickel and palladium complexes. Palladium (O) complexes have been shown to catalyse the reaction of butadiene with alcohols', amines*, carboxylic acids2B3 and active methylene and methyne compounds 4. Although telomerisation of methanol with butadiene in the presence of a Ni” complex has been reportedS, the reaction is, by no ...

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