European journal of inorganic chemistry

Indium (I) Hexafluoropnictates (InPnF6; Pn= P, As, Sb)

Z Mazej

Index: Mazej, Zoran European Journal of Inorganic Chemistry, 2005 , # 19 p. 3983 - 3987

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Citation Number: 8

Abstract

Abstract The colourless compounds InPnF 6 (Pn= P, As, Sb), with In I in a solely fluorine environment, were prepared by reacting In metal with PnF 5 (Pn= P) and displacement of the weaker Lewis acid BF 3 from InBF 4 by a stronger one, PnF 5 (Pn= As, Sb), in anhydrous hydrogen fluoride (aHF). The X-ray powder diffraction analyses show that InPF 6 crystallises in cubic unit cell with a= 8.07 (2) Å, while InAsF 6 crystallises in a rhombohedral unit cell ...