Synthetic Communications

Regioselective Allylation of Ketones

RA Cormier, TE Morris

Index: Cormier, Russell A.; Morris, Theresa E. Synthetic Communications, 1987 , vol. 17, # 14 p. 1673 - 1676

Full Text: HTML

Citation Number: 3

Abstract

Abstract In connection with our work concerning synthesis of insect pheromones, 1 we became interested in reports by Lorette and Howard2 in which were described a method for preparing alpha-allyl ketones. These authors reported that diallyl ketals (4), available by exchange between a ketone (1), allyl alcohol and 2, 2-dimethoxypropane, suffer acid- catalyzed elimination to yield intermediate allyl enol ethers (5/6) which undergo ...

Related Articles:

3, 3'-bis (trisarylsilyl)-substituted binaphtholate rare earth metal catalysts for asymmetric hydroamination

[Gribkov, Denis V.; Hultzsch, Kai C.; Hampel, Frank Journal of the American Chemical Society, 2006 , vol. 128, # 11 p. 3748 - 3759]

Aminyl radical cyclization by means of anodic oxidation. Stereoselective synthesis of cis-1-methyl-2, 5-disubstituted pyrrolidines

[Tokuda, Masao; Yamada, Yasufumi; Takagi, Toshiya; Suginome, Hiroshi; Furusaki, Akio Tetrahedron Letters, 1985 , vol. 26, # 49 p. 6085 - 6088]

Substituent directed oxidative cyclization with cetyltrimethylammonium permanganate: A general approach to the synthesis of γ-and δ-lactones

[Rathore, Rajendra; Vankar, Padma S.; Chandrasekaran, S. Tetrahedron Letters, 1986 , vol. 27, # 34 p. 4079 - 4082]

A New Class of Hypnotics. Unsaturated Carbinols. 1 Part I

[Papa et al. Journal of the American Chemical Society, 1954 , vol. 76, p. 4446,4449]

Regioselective aza-Cope rearrangement of. alpha.-halogenated and nonhalogenated imines

[Welch, John T.; Corte, Bart De; Kimpe, Norbert De Journal of Organic Chemistry, 1990 , vol. 55, # 17 p. 4981 - 4983]

More Articles...