Diastereoselective synthesis of (2S∗)-2-[(R∗)-1H-indol-3-yl (phenyl) methyl]-2, 3-dihydro-1H-inden-1-one
BB Semenov, KA Novikov, KA Lysenko, VV Kachala
Index: Semenov, Boris B.; Novikov, Kirill A.; Lysenko, Konstantin A.; Kachala, Vadim V. Tetrahedron Letters, 2006 , vol. 47, # 20 p. 3479 - 3483
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Citation Number: 7
Abstract
Double asymmetric induction in Michael reactions has been studied. Enantioselective alkylation of a cyclic ketone (1-indanone) with α-phenyl-nor-gramine was carried out. The relative configuration of (2S∗)-2-[(R∗)-1H-indol-3-yl (phenyl) methyl]-2, 3-dihydro-1H-inden- 1-one was established by X-ray diffraction. The relative configuration of (R∗, R∗, S∗)-and (S∗, R∗, S∗)-2-1H-indol-3-yl (phenyl) methyl]-2, 3-dihydro-1H-inden-1-ols was ...
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