Tetrahedron

Facile deprotection of dithioacetals by using a novel 1, 4-benzoquinone/cat. NaI system

K Inamoto, T Yamada, S Kato, S Kikkawa, Y Kondo

Index: Inamoto, Kiyofumi; Yamada, Tetsuya; Kato, Sei-Ichi; Kikkawa, Shoko; Kondo, Yoshinori Tetrahedron, 2013 , vol. 69, # 44 p. 9192 - 9199

Full Text: HTML

Citation Number: 4

Abstract

Abstract The combination of 1, 4-benzoquinone and a catalytic amount of NaI was found to be effective for the deprotection of dithioacetals. The reactions proceeded efficiently under mild, near-neutral reaction conditions, producing a wide range of aryl and alkyl aldehydes and ketones generally in high yields with good functional group compatibility. The method developed therefore represents a general, facile, and highly applicable approach for ...

Related Articles:

Synthesis of Benzo [b] furans by Palladium-NHC Catalyzed Ring Closure of o-Bromobenzyl Ketones

[Farago, Janos; Kotschy, Andras Synthesis, 2009 , # 1 p. 85 - 90]

2, 4, 4, 6-Tetrabromo-2, 5-cyclohexadienone (TABCO), N-bromosuccinimide (NBS) and bromine as efficient catalysts for dithioacetalization and oxathioacetalization of …

[Iranpoor, Nasser; Firouzabadi, Habib; Shaterian, Hamid Reza; Zolfigol Phosphorus, Sulfur and Silicon and Related Elements, 2002 , vol. 177, # 5 p. 1047 - 1071]

Chemoselective thioacetalization using 3-(1, 3-dithian-2-ylidene) pentane-2, 4-dione as an odorless and efficient propane-1, 3-dithiol equivalent under solvent-free …

[Ouyang, Yan; Dong, Dewen; Zheng, Chunbai; Yu, Haifeng; Liu, Qun; Fu, Zhenqian Synthesis, 2006 , # 22 p. 3801 - 3804]

Chemoselective thioacetalisation and transthioacetalisation of carbonyl compounds catalysed by tetrabutylammonium tribromide (TBATB)

[Naik, Sarala; Gopinath, Rangam; Goswami, Mousumi; Patel, Bhisma K. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 11 p. 1670 - 1677]

Chemoselective thioacetalisation and transthioacetalisation of carbonyl compounds catalysed by tetrabutylammonium tribromide (TBATB)

[Naik, Sarala; Gopinath, Rangam; Goswami, Mousumi; Patel, Bhisma K. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 11 p. 1670 - 1677]

More Articles...