Substrate regulation of product distribution in the reactions of arylchromium carbene complexes with alkynes

…, RA Miller, S Chamberlin, TA Brandvold

Index: Bos, Mary Ellen; Wulff, William D.; Miller, Ross A.; Chamberlin, Steven; Brandvold, Timothy A. Journal of the American Chemical Society, 1991 , vol. 113, # 24 p. 9293 - 9319

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Citation Number: 114

Abstract

Abstract: The reactions of arylcarbene complexes with alkynes were examined for six of the nine possible substitution patterns for mom and dioxygenated aryl substituents of the carbene carbon. The product distributions were found to be highly dependent on a number of factors, including solvent, temperature, concentration of alkyne, and the nature of the aryl substituent. The product distributions were determined in nearly all cases for phenol and ...