Absolute rate constants for hydrocarbon autoxidation. 32. On the self-reaction of 1, 1-diphenylethylperoxyl in solution

JA Howard, JHB Chenier…

Index: Howard, J. A.; Chenier, J. H. B.; Yamada, T. Canadian Journal of Chemistry, 1982 , vol. 60, p. 2566 - 2572

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Citation Number: 16

Abstract

The major products of the self-reaction of 1, 1-diphenylethylperoxyl have been determined from product studies of the autoxidation of 1, 1-diphenylethane, induced decomposition of 1, 1-diphenylethyl hydroperoxide, and decomposition of 2, 2, 3, 3-tetraphenylbutane under an atmosphere of oxygen. Overall self-reaction is a complex free-radical process involving the intermediacy of 1, 1-diphenylethoxyl and 1-phenyl-1-phenoxyethoxyl which undergo H- ...

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