Reductive carbonylation of alkenes using zwitterionic rhodium complexes as catalysts

JQ Zhou, H Alper

Index: Zhou, Jian-Qiang; Alper, Howard Journal of the Chemical Society, Chemical Communications, 1991 , # 4 p. 233 - 234

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Abstract

Alkenes react with carbon monoxide, sodium borohydride, propan-2-ol and a catalytic amount of Rh (cod)(η6-PhBPh3)(cod= cyclooctadiene) to give alcohols in fine yields; high regioselectivity for the branched or linear alcohol is usually observed, depending on the organic substrate.

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