SYNTHESIS, SPECTRAL STUDIES AND C—S BOND FISSION THROUGH PUMMERER REACTION OF SOME ALKYL [(SUBSTITUTED BENZYLIDENE) DITHIO] …

GA Gohar

Index: Gohar, Gamal A. Phosphorus, Sulfur and Silicon and the Related Elements, 1993 , vol. 79, # 1,4 p. 171 - 178

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Abstract

Abstract A series of methyl and ethyl [(substituted benzylidene) dithio] diacetates have been synthesized and their structures were identified. Correlation between δ-values of the benzylidene protons and [sgrave]-Hammett values has been found. The internal chemical shift Δ∊ of the methylene protons was found to be correlated linearly with [sgrave]-Hammett constants indicating that the sulfur atom could transmit a polar effect to the substituent. ...