Novel functional group transformations involving alkyl phenyl selenones
A Krief, W Dumont, JN Denis
Index: Krief, Alain; Dumont, Willy; Denis, Jean-Noel Journal of the Chemical Society, Chemical Communications, 1985 , # 9 p. 571 - 572
Full Text: HTML
Citation Number: 22
Abstract
Alkyl phenyl selenones readily undergo substitution reactions, and are valuable precursors of epoxides on reaction with aldehydes in the presence of bases. ... While the reactivity of sulphones is well documented,' little is known about their selenium analogues, namely the sel- enones.2--5 We now report preliminary results concerning the exceptional reactivity of this quite unexplored functional group. We decided to take decyl phenyl selenone (1) as a model ...
Related Articles:
[Kobiki, Yohsuke; Kawaguchi, Shin-Ichi; Ogawa, Akiya Tetrahedron Letters, 2013 , vol. 54, # 40 p. 5453 - 5456]
Synthesis of α-selenoalkyllithium compounds
[Krief, A.; Dumont, W.; Clarembeau, M.; Bernard, G.; Badaoui, E. Tetrahedron, 1989 , vol. 45, # 7 p. 2005 - 2022]
Phenyl selenide anion, a superior reagent for the SN2 cleavage of esters and lactones
[Liotta, Dennis; Sunay, Ustun; Santiesteban, Hector; Markiewicz, William Journal of Organic Chemistry, 1981 , vol. 46, # 13 p. 2605 - 2610]
Simple synthesis of organyl phenyl selenides from exchange resin-supported phenyl selenide anion
[Weber, J. V.; Faller, P.; Kirsch, G.; Schneider, M. Synthesis, 1984 , # 12 p. 1044 - 1045]