Polymerization of substituted phenylacetylenes: Charge transfer complexes of p-dimethylaminophenylacetylene

A Janoušová, MJ Beneš, M Janić…

Index: Janousova,A. et al. Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, p. 1858 - 1861

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Abstract

An investigation was carried out of the thermal and anionic polymerization of substituted phenyl- acetylenes (a-nitro, p-nitro andp-dimethylamino). Thermal polymerization gives rise to conjugated oligomers. Under the conditions of anionic polymerization only dimer is formed from p-dimethyl- aminophenylacetylene. The radical polymerization of the charge-transfer complex of p-dimethyl- arninophenylacetylene with maleic anhydride (molar ratio 2: 3) yielded an ...

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