Reactions of. alpha.-phenylpolynitrotoluenes. 4. o-Nitro rearrangements in the polynitrodiphenylmethanes

LA Kaplan, IA Angres, KG Shipp

Index: Kaplan,L.A. et al. Journal of Organic Chemistry, 1977 , vol. 42, # 7 p. 1262 - 1264

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Abstract

Figure 3. Relative rate for the formation of TNT-in the reaction of TNT with I1 as a function of the concentration of hexadecyltrimethylammonium bromide in aqueous solution at 25 OC. Initial concentrations of TNT and I1 were 2.5 X and 1 XM, respectively. factants. The enhanced rate was more pronounced with the cationic surfactant than the nonionic one (cf. 130 vs. 8). The critical micelle concentration of hexadecyltrimethylammonium bromide is ...