A remarkable solvent effect on the reductive silylation of carboxylic esters. Preparation of 1, 1-bis (trimethylsilyl)-1-alkanols.

I Kuwajima, N Minami, T Abe, T Sato

Index: Kuwajima,I. et al. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 2391 - 2393

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Citation Number: 18

Abstract

Page 1. August, 1978] BULLETIN or THE CHEMICAL SOCIETY or JAPAN, voL. 51 (8), 2391—2393 (1978) 2391 A Remarkable Solvent Effect on the Reductive Silylation of Carboxylic Esters. ... 1 SiMc3 4 5 G SiMe3 —Me,SiOR' Na—Me,SiCI . ——-— R—CO—SiMe3 R—C—O—SiMe, 2 1 7 SiMea Scheme 1. This type of product was isolated by Picard et al. ... Chem. Sea, 99, 4181 (1977); f) N. Minami, T. Abe, and I. Kuwajima, j. Organomet. ...