Well-defined Ir/Pd complexes with a triazolyl-diylidene bridge as catalysts for multiple tandem reactions

A Zanardi, JA Mata, E Peris

Index: Zanardi, Alessandro; Mata, Jose A.; Peris, Eduardo Journal of the American Chemical Society, 2009 , vol. 131, # 40 p. 14531 - 14537

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Citation Number: 98

Abstract

The ligand 1, 2, 4-trimethyl-triazolyl-diylidene has been used for the preparation of a series of three iridium/palladium heterometallic complexes that have been fully characterized. The presence of the two different metals allows tandem processes to be designed by combining reactions that are typically catalyzed by Ir and Pd. Three tandem reactions have been studied: dehalogenation/transfer hydrogenation of haloacetophenones, Suzuki-coupling/ ...