Synthesis and structure of dichloropalladium (II) complexes of heteroleptic N, S-and N, Se-donor ligands based on the 2-organochalcogenomethylpyridine motif, and …

…, AJ Canty, MG Gardiner, BW Skelton, VA Tolhurst…

Index: Jones, Roderick C.; Canty, Allan J.; Gardiner, Michael G.; Skelton, Brian W.; Tolhurst, Vicki-Anne; White, Allan H. Inorganica Chimica Acta, 2010 , vol. 363, # 1 p. 77 - 87

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Citation Number: 17

Abstract

Ligands containing the 2-organochalcogenomethylpyridine motif with substituents in the 4- or 6-position of the pyridyl ring, R4, R6-pyCH2ER1 [R4= R6= H, ER1= SMe (1), SeMe (2), SPh (6), SePh (7); R4= Me, R6= H, ER1= SMe (3), SPh (8), SePh (9); R4= H, R6= Me, ER1= SMe (4), SPh (10), SePh (11); R4= H, R6= Ph, ER1= SMe (5), SPh (12), SePh (13)] are obtained on the reaction of R4, R6-pyMe with LiBun followed by R1EER1. On reaction ...