The Journal of Organic Chemistry

Effective transformation of unactivated alkynes into ketones or acetals with a gold (III) catalyst

Y Fukuda, K Utimoto

Index: Fukuda, Yukitoshi; Utimoto, Kiitiro Journal of Organic Chemistry, 1991 , vol. 56, # 11 p. 3729 - 3731

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Citation Number: 362

Abstract

ArW of thiophenols. Reaction of l, 4-dichlorobenzene with the sodium salt of tert-butyl mercaptan gave compounds 2 and 3 in yields of 89 and 7%, respectively. Thiophenol3 was probably formed from 2 by elimination of isobutene rather than by nucleophilic substitution since no di-tert-butyl sulfide was observed.

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