Chemistry and Synthetic Utility of α-(Dimethylamino) benzylidene and 1-(Dimethylamino) ethylidene Acetals
S Hanessian, E Moralioglu
Index: Wakita, Natsumi; Hara, Shoji Tetrahedron, 2010 , vol. 66, # 40 p. 7939 - 7945
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Citation Number: 34
Abstract
... Ces acetals sont hydrolysks dans le methanol aqueux pour redonner le diol initial. A p H 4-5, le clivage conduit aux benzoates et acetates correspondants probablement par la formation successive d'un ion acyloxonium et d'un orthoacide comme intermediaires. ... VOL. 50, 1972 ...
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