True metal-catalyzed hydroboration with titanium
X He, JF Hartwig
Index: He, Xiaoming; Hartwig, John F. Journal of the American Chemical Society, 1996 , vol. 118, # 7 p. 1696 - 1702
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Citation Number: 130
Abstract
Dicarbonyltitanocene is an efficient and highly selective catalyst for alkyne hydroborations by catecholborane and dimethyltitanocene is an efficient and highly selective catalyst for alkene hydroborations. These results contrast the hydroboration chemistry with other early transition metal complexes that simply lead to decomposition of catecholborane to form diborane and parallel the hydroboration chemistry of permethylcyclopentadienyl ...
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