The Journal of Organic Chemistry

Structural Features Facilitating the Photodecarbonylation of Cyclic Ketˇones1, 2

JE Starr, RH Eastman

Index: Starr,J.E.; Eastman,R.H. Journal of Organic Chemistry, 1966 , vol. 31, p. 1393 - 1402

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Citation Number: 58

Abstract

XXIV was employed to prepare Zindanone (IX) from indene (VIII). Reduction of 2-indanone with lithium and n-propylamine14 gave only a 9% yield of the unsaturated alcohol XI1 accompanied by a large amount of tarry by-product, but when ketone IX was first reduced to 2-indanol (XI) using lithium aluminum hydride, the latter could be reduced with lithium and n- propylamine to give an 85% yield of 4, 5, 6, 7-tetrahydro-2-indanol (XII).

Direct studies of 1, 1-diazenes. Syntheses, infrared and electronic spectra, and kinetics of the thermal decomposition of N-(2, 2, 6, 6-tetramethylpiperidyl) nitrene and N …

[Hinsberg, William D.; Schultz, Peter G.; Dervan, Peter B. Journal of the American Chemical Society, 1982 , vol. 104, # 3 p. 766 - 773]

Tests for free-radical intermediates in the decarbonylation of aldehydes by tris (triphenylphosphine) chlororhodium (I)

[Kampmeier, J. A.; Harris, S. H.; Wedegaertner, D. K. Journal of Organic Chemistry, 1980 , vol. 45, # 2 p. 315 - 318]

Photochemistry of 1, 1-diazenes. Direct and sensitized photolyses of N-(2, 2, 5, 5-tetramethylpyrrolidyl) nitrene, dl-N-(2, 5-diethyl-2, 5-dimethylpyrrolidyl) nitrene, and N …

[Schultz, Peter G.; Dervan, Peter B. Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6660 - 6668]