Journal of Molecular Spectroscopy

Microwave spectrum of trans-nitrosoethylene-15 N and pyrolysis mechanism of chloroacetaldehyde oxime

T Sakaizumi, M Nishikawa, O Ohashi

Index: Sakaizumi, Takeshi; Nishikawa, Motoi; Ohashi, Asamu Journal of Molecular Spectroscopy, 1995 , vol. 171, # 2 p. 518 - 524

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Citation Number: 30

Abstract

The microwave spectrum of trans-nitrosoethylene-15N (nitrosoethene) generated by pyrolysis of chloroacetaldehyde oxime-15N has been observed in the frequency range from 8.0 to 40.0 GHz. The relational constants of the 15N species are determined to be A= 50390 (201), B= 5057.00 (3), and C= 4605.29 (3) MHz. The rs-coordinates (a and b) of the nitrogen atom of trans-nitrosoethylene are determined to be 0.540 (1) and 0.453 Å, respectively. ...