Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system
V Agabekov, W Seiche, B Breit
Index: Agabekov, Vladislav; Seiche, Wolfgang; Breit, Bernhard Chemical Science, 2013 , vol. 4, # 6 p. 2418 - 2422
Full Text: HTML
Citation Number: 27
Abstract
Hydroformylation of alkynes is an underdeveloped atom-economic and redox-neutral method to prepare enals. Applying a new electron poor self-assembling ligand system provides the first general rhodium-catalyst for the chemo-and stereoselective hydroformylation of dialkyl-as well as diaryl-substituted alkynes to furnish enals in excellent chemo-and stereoselectivity.
Related Articles:
[Demchuk, Dmitry V.; Samet, Alexander V.; Chernysheva, Natalia B.; Ushkarov, Vladimir I.; Stashina, Galina A.; Konyushkin, Leonid D.; Raihstat, Mikhail M.; Firgang, Sergei I.; Philchenkov, Alex A.; Zavelevich, Michael P.; Kuiava, Ludmila M.; Chekhun, Vasyl F.; Blokhin, Dmitry Yu.; Kiselyov, Alex S.; Semenova, Marina N.; Semenov, Victor V. Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 2 p. 738 - 755]
1, 2, 3-Triazole analogs of combretastatin A-4 as potential microtubule-binding agents
[Odlo, Kristin; Fournier-Dit-Chabert, Jeremie; Ducki, Sylvie; Gani, Osman A.B.S.M.; Sylte, Ingebrigt; Hansen, Trond Vidar Bioorganic and Medicinal Chemistry, 2010 , vol. 18, # 18 p. 6874 - 6885]
Synthetic approach to enyne and enediyne analogues of anticancer agents
[Provot, Olivier; Giraud, Anne; Peyrat, Jean-Francois; Alami, Mouad; Brion, Jean-Daniel Tetrahedron Letters, 2005 , vol. 46, # 49 p. 8547 - 8550]
[Bui, Vu P; Hudlicky, Tomas; Hansen, Trond V; Stenstrom, Yngve Tetrahedron Letters, 2002 , vol. 43, # 15 p. 2839 - 2841]
[Kato; Kido; Wu; Yoshikoshi Bulletin of the Chemical Society of Japan, 1974 , vol. 47, # 4 p. 1516 - 1521]