Thermal reaction of phenylnitrene with sulphides

…, M Grossi, PC Montevecchi, P Spagnolo

Index: Benati, Luisa; Grossi, Mario; Montevecchi, P. Carlo; Spagnolo, Piero Journal of the Chemical Society, Chemical Communications, 1982 , # 13 p. 763 - 765

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Abstract

Thermolysis of phenyl azide in the presence of sulphides bearing cc-hydrogen atoms leads to the formation of significant amounts of 2-substituted anilines, presumably by Sommelet-Hauser type rearrangements of the intermediate N-phenylsulphimides. ... Reactions of several sulphonyl-, carbonyl-, and acylamino- nitrenes with sulphides leading to sulphimides by singlet attack on the sulphur atom have been observed in a number of