Tetrahedron

The thermal deazetations of fluorinated 2, 3-diazabicyclo [3.2. 0] hept-2-enes

WR Dolbier, DM Al-Fekri

Index: Dolbier, William R.; Al-Pekri, Dheya M. Tetrahedron, 1987 , vol. 43, # 1 p. 39 - 44

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Citation Number: 4

Abstract

Thermal deazetation of difluoro-and tetrafluoro-2, 3-diazabicyclo [3.2. 0] hept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloaddition process. A key