Supramolecular nanovalves controlled by proton abstraction and competitive binding
KCF Leung, TD Nguyen, JF Stoddart…
Index: Coxon,A.C.; Stoddart,J.F. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1977 , p. 767 - 785
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Citation Number: 177
Abstract
The openings to nanosized pores in silica particles are regulated by gatekeeper supermolecules that are controlled by pH stimulation and competitive binding. Controlled release of molecules is demonstrated by using bases and organic and inorganic salts as