Synthesis and carbon-13 nuclear magnetic resonance studies of some bridgehead fluorides: carbon-fluorine coupling constants
EW Della, E Cotsaris, PT Hine
Index: Della,G.W.; Cotsaris,E.; Hine,P.T. Journal of the American Chemical Society, 1981 , vol. 103, p. 4131
Full Text: HTML
Citation Number: 31
Abstract
Abstract: The synthesis of 1-fluorobicyclo [2.2. 1] heptane, 1-fluorobicyclo [3.1. l] heptane, l- fluorobicyclo [2. l. l] hexane, and 1-fluorobicyclo [1. ll] pentane is described. The I3C NMR spectra of these fluorides together with that of I-fluorotricyclo-[3.3. 0.02 s6] octane were examined in order to gauge, in particular, the importance of Fermi contact contributions to the one-bond" CF spin-spin coupling constants. It is found that the magnitude of'J (13C-F) ...
Related Articles:
[Molander, Gary A.; McKie, Jeffrey A. Journal of Organic Chemistry, 1991 , vol. 56, # 13 p. 4112 - 4120]
Reactions of t-Alkyl Hypochlorites with Trisubstituted Phosphines and Phosphites
[Denney,D.B.; DiLeone,R.R. Journal of the American Chemical Society, 1962 , vol. 84, p. 4737 - 4743]
Nitrosation of the N-alkyl-O-acylhydroxylamines. A new deamination method
[White, Emil H.; Ribi, Max; Cho, Lee K.; Egger, Notker; Dzadzic, Petar M.; Todd, Michael J. Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4866 - 4871]
[Molander, Gary A.; McKie, Jeffrey A. Journal of Organic Chemistry, 1991 , vol. 56, # 13 p. 4112 - 4120]
[Molander, Gary A.; McKie, Jeffrey A. Journal of Organic Chemistry, 1991 , vol. 56, # 13 p. 4112 - 4120]