Organometallics

Synthesis and fluxional behavior of [bis (trialkylphosphine) nickelio] anthracene (alkyl= Et, Bu)

A Stanger, KPC Vollhardt

Index: Stanger, Amnon; Vollhardt, K. Peter C. Organometallics, 1992 , vol. 11, p. 317 - 320

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Citation Number: 30

Abstract

The title compounds were prepared from the respective (R3P) 2NiC12 complexes and magnesiumanthra~ ene (THF')~(or anthracene in the presence of Mg or C8K). The assignment of the anthracene proton NMR signals using NOE in conjunction with magnetization-transfer techniques is described. The complexes undergo haptotropic rearrangements in which the (R3P) 2Ni moiety migrates between the two terminal rings of ...