Enzymatic alcoholysis of alkoxymethyl alkanoates: a possible approach for the kinetic resolution of tertiary alcohols
MCR Franssen, ELV Goetheer, H Jongejan…
Index: Franssen, Maurice C.R.; Goetheer, Earl L.V.; Jongejan, Hugo; De Groot, Aede Tetrahedron Letters, 1998 , vol. 39, # 45 p. 8345 - 8348
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Citation Number: 18
Abstract
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The pivaloyloxymethyl and butanoyloxymethyl derivatives of tert-butanol and linalool (1, 4) are readily accepted by hydrolases. Linalool derivative 4b is alcoholysed stereoselectively by Candida rugosa lipase (E=9.7). ... Alkoxymethyl alkanoates obtained from tertiary alcohols (4) ...
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