Ortho-alkylation of acetanilides using alkyl halides and palladium acetate

SJ Tremont, H ur Rahman

Index: Tremont, Samuel J.; Rahman, Hayat Ur Journal of the American Chemical Society, 1984 , vol. 106, # 19 p. 5759 - 5760

Full Text: HTML

Citation Number: 217

Abstract

Palladium-mediated catalysis which is useful in carbon-carbon bond formation usually involves Pdo to Pd" recycle.'The halogenation of azobenzene with palladium chloride represents an intriguing catalytic reaction that does not involve a palladium recycle. 2 A Pd" to PdIV transformation has been postulated for this reaction. We wish to describe a new catalytic carbon-carbon bond-forming reaction that does not involve recycle of palladium ...